The pidgin Facebook plugin does not work properly so far. A single Facebook user actually talks to me with yet another id, every single time he sends me a message. This does not look tested well enough.
I am using pidgin 2.6.2 (libpurple 2.6.2) from fink on Mac OS X, Snow Leopard.
Update / 2010-12-28:
For quite a while Facebook chat has now been reachable through Jabber / XMPP.
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